dildoque (Hive Bee)
08-13-01 12:43
No 204216
      PEA  Bookmark   

http://www.ch.ic.ac.uk/local/projects/s_thipayang/synth.html

Reaction 3 looks interesting. Would it be possible to use methoxyphenol instead of indole ?
 
 
 
 
    Rhodium
(Chief Bee)
08-13-01 12:58
No 204220
      Re: PEA  Bookmark   

In some instances perhaps. See the text ../rhodium/chemistry /dmane.html for more information on a related reagent. Could you find any other references on this reaction?
 
 
 
 
    dildoque
(Hive Bee)
08-14-01 12:28
No 204529
      Re: PEA  Bookmark   

I found this :


Is there any kind of rearrangement to move the -CH2-CH2-NO2 in the right position ?