Belial (Newbee)
04-26-02 18:51
No 301883
      THF - GBL (FeSO4)/H202  Bookmark   

This was brought up by foxy during an intereting discussion on routes to GBL

"THF (0.5 mol) and 0.1 mol FeSO4 in H2O was treated
dropwise with 1.05 mol 30% H2O2 at (less than)30C and
the mixt. stirred 3 h at 30C and 8 h at 45C to give
61.6% g-butyrolactone."

Would there be room for scaleability here, or would the chance of evil peroxide formation be too great?
Any other perveivable problems with scaling?

Respect
Belial!
 
 
 
 
    ChemicalSolution
(Hive Bee)
04-27-02 19:00
No 302338
      ...  Bookmark   

Do you have a reference for that?
 
 
 
 
    foxy2
(Distinctive Doe)
04-27-02 19:46
No 302360
      UTFSE  Bookmark   

I posted it, UTFSE

Those who give up essential liberties for temporary safety deserve neither liberty nor safety
 
 
 
 
    Belial
(Newbee)
04-27-02 20:07
No 302372
      Reference  Bookmark   

g-Butyrolactone from tetrahydrofuran.    
Hara, Hiroshi.  (Japan). 
Japanese Patent  JP  53087347  19780801

As raised by foxy in post # 243627