3base (Hive Bee)
06-10-02 13:14
No 319375
      proposed: MDP2Pol --> MDP2P  Bookmark   

3,4-diMeO-P1Pol --> 3,4-diMeO-P1P

3,4-diMeO-P1Pol ... was oxidized to 3,4-diMeO-P1P ... by
dissolving it in 120mL of ether and treating it with 6.0g(0.02mol)
of potassium dichromate dissolved in 150mL of water containing
10g of sulfuric acid. After stirring for 5h at 25C, the ether
layer was washed with 1.0M aq.KOH, dried, and removed in vacuo.


Chem Res Toxicol, 1996 9(1): 109-113
"Mechanism of Isomerization of 4-Propyl-o-quinone to Its
Tautomeric p-Quinone Methide"
Judy L. Bolton, Hao Ming Wu, Li Qing Hu
 
 
 
 
    Rhodium
(Chief Bee)
06-10-02 13:17
No 319376
      3,4-MeO-Propiophenone  Bookmark   

Are you suggesting any special use for 3,4-MeO-Propiophenone?
 
 
 
 
    3base
(Hive Bee)
06-10-02 13:25
No 319378
      is propiophenone of any use ?  Bookmark   

> Are you suggesting any special use for 3,4-MeO-Propiophenone?

no, i don't know if propiophenone is of any use ?
this rnx just looks applicable for the conversion of
MDP2Pol --> MDP2P and other MeO-substituted P2Pol's.
 
 
 
 
    terbium
(Old P2P Cook)
06-10-02 16:27
No 319418
      Different sensitivities.  Bookmark   

this rnx just looks applicable for the conversion of
MDP2Pol --> MDP2P and other MeO-substituted P2Pol's.

Do you think that you can compare P2Pol's and P1Pol's this way. The P2P's have the benzylic hydrogens that are sensitive to oxidation. Wouldn't this process be likely to take a P2P to benzoic acid?