Does anyone have the time to ponder whether something useful could be done with 1-phenyl-2-thiourea?
I had in mind this unwatched compound being reacted in such a way that the yield would be bromobenzene + by products.
In a similar fashion, I wonder whether 1-allylthiourea could yield somehow allylbromide/allylchloride/allyliodide?
See what I'm getting at here?
followed by grignard reagent
Safety data for 1-phenyl-2-thiourea
Synonyms: phenylthiocarbamide, phenylthiourea, alpha-phenylthiourea, N-phenylthiourea, 1-phenylthiourea, PTC, PTU, U 6324, USAF EK-1569
Molecular formula: C7H5NHCSNH2
CAS No: 103-85-5
Appearance: white crystalline powder
Melting point: 154 C
Density (g cm-3): 1.3
Water solubility: negligible
Stable. Incompatible with strong acids, strong oxidizing agents, strong bases.
Poison. Highly toxic - may be fatal if swallowed or inhaled. Note low LD50s below. Experimental teratogen. Irritant.
(The meaning of any abbreviations which appear in this section is given here.)
ORL-RAT LD50 3 mg kg-1
IPR-RAT LD50 5 mg kg-1
ORL-MUS LD50 10 mg kg-1
IPR-MUS LD50 25 mg kg-1
ORL-RBT LD50 40 mg kg-1
(The meaning of any risk phrases which appear in this section is given here.)
R23 R24 R25.
(The meaning of any UN hazard codes which appear in this section is given here.)
UN No 2767. Packing group I. Hazard class 6.1.
Safety glasses, gloves, good ventilation, dust mask if powdered product may get into the atmosphere.
Judging by the data you should find something else to cook with so you may cook tomorrow...........java