Rhodium (Chief Bee)
10-18-03 10:42
No 414904
      Hydroamination routes to Amphetamines & PEAs  Bookmark   

Review: Base-Catalyzed Hydroamination of Olefins: An Environmentally Friendly Route to Amines
Advanced Synthesis & Catalysis, 344(8), 795-813 (2002) (../rhodium/pdf /base-cat.hydroamination.review.pdf)

A Base-Catalyzed Domino-Isomerization–Hydroamination Reaction – New Synthetic Route to Amphetamines
Tetrahedron 56(29), 5157-5162 (2000) (../rhodium/pdf /hydroamination.allylbenzene2amphetamines.pdf)

Post 271694 (foxy2: "Re: here it is: direct amination of allylbenzene", Chemistry Discourse)
Post 465442 (Rhodium: "Hydroamination Route to Amphetamines", Chemistry Discourse)

Amphetamines and phenyl-2-propanones from 1-phenylpropyne and amines
Chem. Soc. Rev., 2003, 32, 104–114 (../rhodium/pdf /catalytic.hydroamination.alkynes.pdf)

Hydroamination of Cinnamylalcohol (http://www.unibas.ch/mdpi/ecsoc-3/a0025/a0025.htm)

Photoinduced amination of styrenes to phtalimide-protected phenethylamines
Post 429395 (Rhodium: "Photophtalimidation of styrenes to PEAs", Serious Chemistry)

An Ammonia Equivalent for the Dimethyltitanocene-Catalyzed Intermolecular Hydroamination of Alkynes
Post 434626 (ChemisTris: "Dimethyltitanocene cat. hydroamination of alkynes", Novel Discourse)
Org. Lett. 2(13), 1935-1937 (2000) (../rhodium/pdf /dimethyltitanocene-hydroamination.pdf)

Synthesis of allylic amines through the palladium-catalyzed hydroamination of allenes
Tetrahedron Letters 36(22), 3857-3860 (1995) (../rhodium/pdf /hydroamination.allenes.pdf)

Riken Review No. 42, pp 53-56 (2001) (../rhodium/pdf /ruthenium.hydroamination.1-alkynes.pdf)

Ruthenium complexes that efficiently catalyze hydration and hydroamination of 1-alkynes have been found. The hydration described here is the first example of anti-Markovnikov regioselectivity to produce aldehydes. A mechanism involving Ru(IV)-hydride-vinylidene intermediate is proposed. A highly practical catalytic hydroamination method has also been developed which was applied to synthesis of nitrogen containing heterocycles.